Diffusion data were presented for 18 elements implanted into SiO2 layers that had been thermally grown on Si and annealed at 300 to 1000C (table 1). Most of the species studied, (Be, B, Al, Sc, Ti, V, Zn, Ga, Mo), exhibited negligible diffusion over the temperature range used. In general, it was shown here that the diffusivity of dopants or impurities in SiO2 was significantly smaller than that in Si. However, it was also observed that several elements (Rb, In) had a higher diffusivity in SiO2 than in Si. Because Ga and In were both used as sources for focused ion beam analyses, the lack of Ga diffusion and the movement of In in SiO2 was of interest.

Diffusion of 18 Elements Implanted into Thermally Grown SiO2. H.G.Francois-Saint-Cyr, F.A.Stevie, J.M.McKinley, K.Elshot, L.Chow, K.A.Richardson: Journal of Applied Physics, 2003, 94[12], 7433-9

Table 1

Diffusivities of Various Elements Implanted into SiO2

 

Diffusant

Energy (keV)

Dose (/cm2)

Temperature (C)

D (cm2/s)

11B

50

1.0 x 1015

1000

< 6 x 10-18

27Al

50

1.0 x 1014

500

< 5 x 10-18

40Ca

150

1.0 x 1014

1000

3.5 x 10-16

45Sc

150

1.0 x 1014

1000

1.1 x 10-18

48Ti

150

1.0 x 1014

1000

< 6 x 10-19

51V

150

1.0 x 1014

1000

< 1.8 x 10-17

55Mn

150

1.1 x 1014

1000

8.8 x 10-17

69Ga

180

8.0 x 1013

1000

< 6.0 x 10-18

98Mo

180

8.9 x 1013

1000

< 8 x 10-19