The serial sectioning technique was used to study the diffusion of 35SO42- ions in single crystals, in the intrinsic range. The results (table 152) could be described by:
D (cm2/s) = 0.065 exp[-1.12(eV)/kT]
M.Bénière, F.Bénière, M.Chemla: Solid State Communications, 1973, 13[9], 1339-43
Table 152
Diffusivity of SO4 in NaCl Crystals
Temperature (C) | D (cm2/s) |
741.7 | 1.73 x 10-7 |
732.2 | 1.56 x 10-7 |
722.1 | 1.40 x 10-7 |
716.4 | 1.19 x 10-7 |
699.2 | 1.01 x 10-7 |
681.7 | 7.45 x 10-8 |
662.1 | 6.31 x 10-8 |
645.7 | 4.67 x 10-8 |
607.0 | 2.33 x 10-8 |
556.1 | 1.02 x 10-8 |
541.1 | 7.39 x 10-9 |