By using the method of desorption from previously saturated specimens, the coefficients of diffusion were determined in single crystals at 473 to 823K. The data (tables 168 and 169) could be described by:
3He: D (cm2/s) = 1.8 x 10-2 exp[-0.36(eV)/kT]
4He: D (cm2/s) = 1.5 x 10-2 exp[-0.36(eV)/kT]
L.V.Gulin, P.V.Volobuev, I.A.Korolev, P.E.Suetin: Fizika Tverdogo Tela, 1977, 19[4], 1017-20
Table 168
Diffusivity of He in RbCl Single Crystals
Isotope | Temperature (K) | D (cm2/s) |
3He | 823 | 1.12 x 10-4 |
3He | 773 | 7.69 x 10-5 |
3He | 723 | 5.48 x 10-5 |
3He | 673 | 3.54 x 10-5 |
3He | 623 | 2.27 x 10-5 |
3He | 573 | 1.15 x 10-5 |
3He | 523 | 0.65 x 10-5 |
3He | 473 | 0.20 x 10-5 |
4He | 823 | 9.48 x 10-5 |
4He | 773 | 6.52 x 10-5 |
4He | 723 | 4.80 x 10-5 |
4He | 673 | 2.91 x 10-5 |
4He | 623 | 1.99 x 10-5 |
4He | 573 | 0.96 x 10-5 |
4He | 523 | 0.62 x 10-5 |
4He | 473 | 0.17 x 10-5 |
Table 169
Isotope Effect for 3He and 4He Diffusion
in RbCl Single Crystals
Temperature (K) | D3/D4 |
823 | 1.18 |
773 | 1.18 |
723 | 1.14 |
673 | 1.22 |
623 | 1.14 |
573 | 1.20 |
523 | 1.05 |
473 | 1.18 |