The conductivities of pure and doped single crystals were measured between room temperature and 900C (table 186). The results were in accordance with the presence of anti-Frenkel disorder.
W.Bollmann, P.Görlich, W.Hauk, H.Mothes: Physica Status Solidi A, 1970, 2[1], 157-70
Table 186
Activation Energies for Ionic Conduction
in Pure and Doped CaF2 Crystals
Dopant | Region | Q (eV) |
- | intrinsic | 1.92 |
CaO | dissociation | 0.55 |
CaO | association | 0.99 |
NaF | dissociation | 0.55 |
NaF | association | 0.93 |
YF3 | dissociation | 1.02 |
YF3 | association | 1.32 |