Both the bond-valence method and the reverse Monte Carlo method had proven to be useful tools for the investigation of the interplay between the microscopic structure and the transport properties in solid electrolytes. A combination of these two approaches opened a way for a deeper understanding of ion transport, especially in amorphous solid electrolytes, where the lack of reliable structural information so far had impeded minute atomistic descriptions of transport mechanisms. The possibilities and limitations of this new approach were considered. Special emphasis was put on the requirements for the consistent determination of bond-valence parameters that as necessary reflected the bond softness. For various Ag+ ion conducting glasses, using bond softness sensitive bond-valence parameters, pathways were found for ion transport in the reverse Monte Carlo produced structural models of the glasses. From the volume fraction of these pathways, it was possible to predict both the absolute value and the activation energy of the ionic conductivity. Simulations of ion transport as random walks within the bond-valence pathway network shed further light on the transport process and provided a complementary way to predict the conductivity from structural models.

Pathway Models for Fast Ion Conductors by a Combination of Bond Valence and Reverse Monte Carlo Methods. S.Adams, J.Swenson: Solid State Ionics, 2002, 154-155, 151-9