It was shown that small concentrations of Pb, Cl or S (table 246) did not affect the activation energy for electrical conduction and hardly changed the phase transition temperature. It was suggested that the dopants, which formed solid solutions with the host, produced little change in the stability and conductivity of the electrolyte at room temperature, within the solid solution range.

V.N.Zagarodnev, N.V.Lichkova, E.B.Yakimov: Izvestiya Akademii Nauk - Neorganicheskie Materialy, 1986, 22[9], 1538-40 (Inorganic Materials, 1986, 22[9], 1349-51)

 

 

Table 246

Conductivity of Ag4RbI5 with Pb, Cl or S Additions at 293K

 

Compound

x (mol%)

σ (S/cm)

Ag4-xPbx/2RbI5

1

0.31

Ag4-xPbx/2RbI5

20

0.25

Ag4-xPbx/2RbI5

50

0.15

Ag4CsxRb1-xI5

1

0.27

Ag4CsxRb1-xI5

5

0.27

Ag4CsxRb1-xI5

10

0.27

Ag4CsxRb1-xI5

15

0.24

Ag4CsxRb1-xI5

30

0.20

Ag4ClxRbI5-x

5

0.31

Ag4ClxRbI5-x

10

0.26

Ag4ClxRbI5-x

50

0.10

Ag4ClxRbI5-x

100

0.01

Ag4SxRbI5-2x

1

0.30

Ag4SxRbI5-2x

5

0.29

Ag4SxRbI5-2x

10

0.28

Ag4SxRbI5-2x

20

0.27

Ag4SxRbI5-2x

50

0.24

Ag4SxRbI5-2x

70

0.16

Ag4SxRbI5-2x

100

0.12

Ag4+xSxRbI5-x

1

0.30

Ag4+xSxRbI5-x

5

0.29

Ag4+xSxRbI5-x

10

0.29

Ag4+xSxRbI5-x

20

0.27

Ag4+xSxRbI5-x

50

0.26

Ag4+xSxRbI5-x

100

0.17