It was demonstrated that H diffusion in hydrogenated amorphous material was trap-controlled. A 1.4eV barrier was measured for deep D emission to a transport level in D-doped amorphous material. It was shown that light-enhanced diffusion in this material was caused by the light-enhanced de-trapping of H, and not by heating of the sample. Estimates were obtained for the free-H diffusion coefficient (3 x 10-8cm2/s), the mean H displacement between deep trapping events (25nm), and for other parameters that affected the measured H diffusion coefficient in this material.

H.M.Branz, S.E.Asher, B.P.Nelson: Physical Review B, 1993, 47[12], 7061-6

 

Table 165

Diffusivity of D in Si

 

Source

T (C)

D (cm2/s)

plasma

350

3.4 x 10-15

plasma

275

8.7 x 10-16

plasma

225

3.1 x 10-16

plasma

200

1.8 x 10-16

plasma

200

1.7 x 10-16

plasma

175

9.4 x 10-17

plasma

175

8.3 x 10-17

plasma

175

7.5 x 10-17

layer

350

1.5 x 10-15

layer

300

2.2 x 10-16

layer

300

2.0 x 10-16

layer

250

3.1 x 10-17