The real-time detection of H motion and bonding was carried out by using capacitance-voltage profiling of various Schottky and metal-insulator capacitors during low-energy H-ion beam injection into the barrier metallization. Numerical modelling indicated that an appreciable fraction of the H interstitials were positively charged, and that bonding of these species with charged B acceptors involved the large cross-section which was to be expected of a Coulomb capture process. The H diffusivity (table 173) at 300K was about 10-10cm2/s. This value was consistent with extrapolations of high-temperature diffusivity data.
C.H.Seager, R.A.Anderson: Applied Physics Letters, 1988, 53[13], 1181-3
Table 173
Diffusivity of H in Si
T (C) | D (cm2/s) |
57 | 5.3 x 10-10 |
57 | 3.1 x 10-10 |
52 | 2.5 x 10-10 |
42 | 2.6 x 10-10 |
22 | 1.3 x 10-10 |
10 | 8.1 x 10-11 |
4 | 6.2 x 10-11 |
0 | 3.8 x 10-11 |
0 | 3.0 x 10-11 |