An unsteady-state gas-liquid metal diffusion cell technique was used to determine the rates of absorption of H in stagnant liquid Fe and in several binary alloys. The rates were found to be controlled by the diffusion of H in the liquid phase, thus permitting the Arrhenius parameters to be calculated, giving:
1550-1680C: D (cm2/s) = 4.37 x 10-3 exp[-4.134(kcal/mol)/RT]
P.J.Depuydt, N.A.D.Parlee: Metallurgical Transactions, 1992, 3[2], 525-32
Table 21
Diffusivity of H in Molten Fe
Temperature (C) | D (cm2/s) |
1560 | 3.30 x 10-3 |
1600 | 3.51 x 10-3 |
1650 | 3.73 x 10-3 |