The permeability was measured for pressure differentials ranging from 0.6 to 12000Pa and for temperatures of between 497 and 933K. A square-root dependence of the permeability upon the driving pressure was observed at higher pressures. The data could be described by:
P (μmol/m s kPa½) = 2.698 x 100 exp[-59.405(kJ/mol)/RT]
The pressure at which this relationship no longer applied depended upon the H purity.
E.H.Van Deventer, V.A.Maroni: Journal of Nuclear Materials, 1980, 92[1], 103-11
Table 107
Permeation Parameters for AISI321
Cold-Rolling (%) | α' (%) | Po (mol/msMPa½) | E (kJ/mol) |
0 | 0 | 2.44 x 10-4 | 62.70 |
21 | 9.3 | 9.24 x 10-5 | 53.50 |
34 | 26 | 2.06 x 10-4 | 54.40 |
54 | 51 | 1.22 x 10-4 | 46.88 |
65 | 55 | 6.75 x 10-5 | 44.26 |