An investigation was made of permeation through 12%Ni alloy membranes which had various structures. The activation energy for D permeation through a martensitic structure at 600 to 800K was 18kcal/mol. The energies for H and D permeation through cold-worked material, at temperatures of between 800 and 900K, were 57 and 42kcal/mol, respectively. The equivalent values for permeation through an austenitic structure, at temperatures of between 800 and 1200K, were 30 and 32kcal/mol.
V.J.Kosheleva, P.V.Geld, V.A.Goltsov, R.A.Ryabov: Metody Opred. Issled. Sostoyaniya Gazov Metal., 1968, 253-6
Table 139
Diffusion Parameters for 63Ni in the Fe-Ni System
Ni (at%) | Do (cm2/s) | E (kJ/mol) |
0 | 1.12 | 283.5 |
14.9 | 1.88 | 289.4 |
29.7 | 2.36 | 291.9 |
29.7 | 17.70 | 324.1 |
45.3 | 8.04 | 303.4 |
60.5 | 7.76 | 300.5 |
70.0 | 13.90 | 305.3 |
75.3 | 13.31 | 307.3 |
79.8 | 8.73 | 301.5 |
90.0 | 7.67 | 299.6 |
100.0 | 3.44 | 290.0 |