The diffusion of 59Fe in the amorphous metal was studied at 533 to 643K. Depth profiling of the as-implanted or diffusion broadened profiles was carried out by using serial sectioning ion beam sputtering techniques. It was found that the diffusivities between the above temperatures ranged from 3.6 x 10-24 to 1.2 x 10-20m2/s. Special attention was paid to the effect of pre-annealing (table 151). In as-quenched specimens, the diffusivity increased markedly with increasing diffusion time, to an almost constant value. The temperature dependence could be described by:
D (m2/s) = 2.7 x 10-2 exp[-2.4(eV)/kT]
J.Horvath, H.Mehrer: Crystal Lattice Defects and Amorphous Materials, 1986, 13[1], 1-14
Table 152
Diffusivity of 32P in Fe40Ni40B20
Temperature (K) | Diffusivity (m2/s) |
573 | 1.4 x 10-23 |
593 | 1.5 x 10-22 |
610 | 2.3 x 10-21 |
611 | 5.8 x 10-22 |
630 | 1.1 x 10-21 |
631 | 1.8 x 10-21 |
635 | 5.6 x 10-21 |
644 | 1.7 x 10-20 |
Table 153
Diffusion of Si in Fe40Ni40B20
Temperature (K) | D (m2/s) |
593 | 1.4 x 10-23 |
603 | 2.3 x 10-23 |
609 | 7.1 x 10-23 |
613 | 7.0 x 10-23 |
632 | 5.3 x 10-22 |
634 | 8.4 x 10-22 |
643 | 7.1 x 10-2l |