Interdiffusion data for the zeta phase at 900 to 1050C were determined by using aluminized vapor/solid diffusion-couples and electron microprobe techniques. It was found that the Arrhenius plot was straight, and that the results (table 57) could be described by:
D(cm2/s) = 219 exp[-58.4(kcal/mol)/RT]
An unusual feature of the data was that, at 1000C, the values were 2 orders of magnitude greater than those for other phases in the system.
R.K.Bamola, L.L.Seigle: Metallurgical Transactions A, 1989, 20[11], 2561-3
Table 43
Bulk Diffusion of 59Fe in an Icosahedral Al-Cu-Fe Alloy
Temperature (C) | D (cm2/s) |
799 | 5.2 x 10-10 |
752 | 8.6 x 10-11 |
703 | 3.3 x 10-11 |
658 | 6.0 x 10-12 |
642 | 3.2 x 10-12 |
612 | 1.2 x 10-12 |
590 | 6.1 x 10-13 |
568 | 2.0 x 10-13 |
514 | 1.9 x 10-14 |
475 | 2.6 x 10-15 |