A study was made of the diffusion of D and H by making Gorsky-effect measurements. It was found that the diffusivity of H, at temperatures of between -60 and 200C, could be described by:
D (cm2/s) = 2.5 x 10-3 exp[-0.226(eV)/kT]
The diffusivity of D, within the same temperature range, could be described by:
D (cm2/s) = 1.7 x 10-3 exp[-0.206(eV)/kT]
J.Völkl, G.Wollenweber, K.H.Klatt, G.Alefeld: Zeitschrift für Naturforschung A, 1971, 26[5], 922-3
Table 230
Parameters for H Diffusion in β-Pd as a Function of Pressure
Pressure (bar) | Do (cm2/s) | E (kcal/g-atom) |
1 | 1.12 | 5.24 |
40 | 1.6 | 5.52 |
100 | 5.2 | 6.32 |
195 | 16 | 7.07 |
315 | 27 | 7.45 |
450 | 14 | 7.09 |