Migration in foils was measured at 0 to 100C by using an electrochemical time-lag method (table 311). A modified strain model indicated that the tetrahedral sites in body-centered cubic lattices had to be assumed to be stable positions for dissolved H. Elementary jumps, from one tetrahedral site to the next, passed directly through a tetrahedral plane. This model described qualitatively the experimental results, with respect to the order of the activation energies for H diffusion in these metals.
N.Boes, H.Züchner: Zeitschrift für Naturforschung A, 1976, 31[7], 760-8
Table 313
Parameters for H Diffusion in VHx
x | Do (cm2/s) | E (eV) |
0.17 | 4.3 x 10-4 | 87 |
0.22 | 4.0 x 10-4 | 89 |
0.31 | 3.8 x 10-4 | 89 |
0.38 | 4.4 x 10-4 | 106 |
0.51 | 5.2 x 10-4 | 121 |
0.68 | 4.7 x 10-4 | 132 |