Migration in foils was measured at 0 to 100C by using an electrochemical time-lag method (table 311). A modified strain model indicated that the tetrahedral sites in body-centered cubic lattices had to be assumed to be stable positions for dissolved H. Elementary jumps, from one tetrahedral site to the next, passed directly through a tetrahedral plane. This model described qualitatively the experimental results, with respect to the order of the activation energies for H diffusion in these metals.

N.Boes, H.Züchner: Zeitschrift für Naturforschung A, 1976, 31[7], 760-8

 

Table 313

Parameters for H Diffusion in VHx

 

x

Do (cm2/s)

E (eV)

0.17

4.3 x 10-4

87

0.22

4.0 x 10-4

89

0.31

3.8 x 10-4

89

0.38

4.4 x 10-4

106

0.51

5.2 x 10-4

121

0.68

4.7 x 10-4

132