The Ni self-diffusion coefficient in Si–Ni melts was measured (table 7), for compositions up to 20at%Ni, from 270K below to 200K above the liquidus temperature using quasi-elastic neutron scattering and electromagnetic levitation. The Ni self-diffusion coefficients were of the order of 10-8m2/s and essentially independent of the Ni concentration. The diffusion coefficients, calculated from viscosity data on pure liquid Si via the Stokes–Einstein relationship, compared well with the Ni self-diffusion obtained here. This indicated a strong correlation between the mobility of the Si and Ni atoms.
Nickel Self-Diffusion in Silicon-Rich Si–Ni Melts. A.I.Pommrich, A.Meyer, D.Holland-Moritz, T.Unruh: Applied Physics Letters, 2008, 92[24], 241922
Table 8
Diffusion of Cu in SiC
Isotope | Temperature (K) | D (m2/s) |
64Cu | 1373 | 2.10 x 10-17 |
67Cu | 1273 | 1.61 x 10-17 |
67Cu | 1173 | 1.15 x 10-17 |
67Cu | 1073 | 8.41 x 10-18 |
67Cu | 973 | 5.09 x 10-18 |
67Cu | 873 | 2.74 x 10-18 |
67Cu | 773 | 1.36 x 10-18 |
67Cu | 623 | 2.66 x 10-19 |