Hydrogen gas driven permeation through the fine-grain graphites MPG-8 and
R5710, and through CFC NB31 in two main directions was investigated for sample
thicknesses of 1–7mm and pressures from 10−2 to 10Pa. The gas driven permeation
occurred through the carbon-base materials by the hydrogen molecular gas flow
through the internal porosity network rather than hydrogen atom diffusion through
the graphite lattice. The permeabilities of MPG-8 and Nb31 were of the same
order, while the permeability of R5710 was two orders of magnitude less. The
specific bulk conductivity was about 5 x 1015molecules/smPa for MPG-8; 8 x
1013molecules/smPa for R5710; 1016molecules/smPa for Nb31 along ex-pitch (x)
fibers after taking into account the perforated surface layer and 8 x
1015molecules/smPa for Nb31 along needled (z) fibers.
Gas-Driven Hydrogen Isotopes Permeation Through Different Carbon Materials.
A.V.Spitsyn, A.V.Golubeva, M.Mayer, A.A.Skovorod: Journal of Nuclear
Materials, 2009, 390-391, 701-4