Vacancies and vacancy clusters produced by carbon ion implantation in highly
oriented pyrolytic graphite, and their annealing behaviour associated with the
ferromagnetism of the implanted sample were studied using positron annihilation
in conjunction with ferromagnetic moment measurements using a superconducting
quantum interferometer device magnetometer. The results indicate that the
magnetic moments were closely correlated to the existence of the vacancy defects
in the samples and this was supported by theoretical calculations using density
functional theory. The mechanism of magnetic order in the implanted sample was
discussed.
Correlation Between the Vacancy Defects and Ferromagnetism in Graphite.
X.Yang, H.Xia, X.Qin, W.Li, Y.Dai, X.Liu, M.Zhao, Y.Xia, S.Yan, B.Wang:
Carbon, 2009, 47[5], 1399-406