Synchrotron X-ray topography, transmission electron microscopy, Nomarski
optical microscopy and defect selective etching analysis were applied to investigate
the nucleation and propagation of carrot defects, basal plane Frank-type defects,
polytype inclusions and basal plane dislocations in 4H-SiC epitaxial growth. In the
development of the 4H-SiC fast epitaxial growth technique, a very high growth rate
of up to 250μm/h was obtained in a newly developed vertical hot-wall-type reactor
under low system pressure using a H2 + SiH4 + C3H8 system. Good thickness and
impurity doping uniformity were also obtained simultaneously over a large area,
with the retention of a high growth rate. A 4H-SiC epilayer virtually free from
basal plane dislocations was obtained on a 4° off Si-face substrate.
Formation of Extended Defects in 4H-SiC Epitaxial Growth and Development of a
Fast Growth Technique. H.Tsuchida, M.Ito, I.Kamata, M.Nagano: Physica Status
Solidi B, 2009, 246[7], 1553-68