An analysis was made of point-defect induced magnetic after-effect processes in
as-grown monocrystalline titano-magnetite (Fe2.8-DTi0.2O4) containing B-site
vacancies (D < 0.005). In a previous experiment these processes, near to 450, 200
and 65K, were completely recovered in the course of systematic annealing up to
1200K. Analysis of respective annealing kinetics suggested their association with
vacancy- (450K) and interstitial-based (200K) defect reorientations, including
modified electron hopping (65K). The present study was performed in order to
check the previously developed relaxation model by low-temperature (80K)
electron irradiation of the pre-recovered crystal and investigating whether the
point-defect relaxation of the initial as-grown state could be reconstituted.
Magnetic after-effect analyses, based upon systematic sample annealing at 80 to
1200K proved radiation-induced reproduction of related processes. Partial
modifications of respective process genealogies may be conveniently assigned to
the alternative techniques of defect induction, i.e. high-temperature crystal growth
in thermal equilibrium or out-of-equilibrium, low-temperature e--irradiation.
Impact of Irradiation-Induced Point Defects on Electronically and Ionically
Induced Magnetic Relaxation Mechanisms in Titano-Magnetites. F.Walz,
V.A.M.Brabers, H.Kronmüller: Physica Status Solidi A, 2008, 205[12], 2934-42