LiMn2O4 thin films were deposited on Au substrates by pulsed laser deposition.

The Li-ion chemical diffusion coefficients of the films, DLi, were measured by

cyclic voltammetry, galvanostatic intermittent titration technique, potentiostatic

intermittent titration technique and electrochemical impedance spectroscopy. It was

found that the DLi values by cyclic voltammetry and potentiostatic intermittent

titration were of the order of 10−13cm2/s, and those by electrochemical impedance

spectroscopy and galvanostatic intermittent titration technique were in the ranges

of 10−13 to 10−11 and 10−14 to 10−11cm2/s, respectively.

Li-Ion Diffusion Kinetics in LiMn2O4 Thin Films Prepared by Pulsed Laser

Deposition. J.Xie, K.Kohno, T.Matsumura, N.Imanishi, A.Hirano, Y.Takeda,

O.Yamamoto: Electrochimica Acta, 2008, 54[2], 376-81