The electrical conductivity behaviour in the para-electric state was investigated in
lanthanum modified lead zirconate titanate ceramics, considering the universal
relaxation law. The contribution of conductive processes to the dielectric response
for the low-frequency range was discussed taking into account the oxygen
vacancies mechanism. The activation energies for the thermally hopping and
conductivity processes were obtained. The results for the frequency dependence of
the conductivity suggested at the oxygen vacancy hopping processes, due to
relaxations in oxygen vacancy-related dipoles, being mainly responsible for the
conduction behaviour in the studied system.
Ionized Oxygen Vacancy-Related Electrical Conductivity in
(Pb1−xLax)(Zr0.90Ti0.10)1−x/4O3 Ceramics. A.Peláiz-Barranco, J.D.S.Guerra, R.López-
Noda, E.B.Araújo: Journal of Physics D, 2008, 41[21], 215503