Twin domains form during the second order structural phase transition between socalled
high symmetric tetragonal phases and low symmetric orthorhombic phases
in YBCOx (YBa2Cu3O6+x, 0 < x < 1). A new analytical approach to coherence
effects in diffraction from a twinned model of YBCOx sample was presented and it
was shown that, for a small mean width of the twin domains, and small strains,
coherence effects gave rise to extra peaks between {h00} reflections (central peak)
such that their intensity died away as the strain and the mean width of the twin
domain were increased. Therefore in diffraction studies of phase characterization
or lattice constants, the coherence effects must be taken into account. Researchers
who were interested in “structural phase transitions” involving reduction in crystal
symmetry may find it necessary to consider the “width of twin domains” as a new
kind of order parameter.
Coherence Effects of Twin Domains in Diffraction from High Tc YbCox.
B.Khoshnevisan: Physica C, 2008, 468[21], 2187-90