Dislocations were of scientific and technological interest due to their unusual
physical properties, which were quite different from those in the bulk. It is,
therefore, expected to use dislocations as nanowires which provide functional
properties in a crystal. Here, high densities of dislocations were introduced in oxide
single crystals by high-temperature plastic deformation. Insulating sapphire and
YSZ single crystal were used as model systems. The electron and ion
conductivities were measured for the dislocation introduced crystals respectively. It was found that the dislocations with Ti segregation in sapphire crystal showed
excellent electrical conductivity and dislocations themselves in YSZ crystal
improved the ionic conductivity. This technique has a potential to be applied for
any crystals because of its simplicity, and will be expected to give special and
unprecedented properties to common materials.
Oxide Ceramics with High Density Dislocations and Their Properties. Y.Ikuhara:
Materials Transactions, 2009, 50[7], 1626-32