It was pointed out that previously published radiotracer results for self diffusion in Si were limited to a relatively narrow temperature range and varied widely. In order to obtain more reliable data over a wide temperature range, the sputter sectioning technique was used. The specimens used were essentially dislocation-free and p-type. Gaussian penetration profiles were observed and the diffusion coefficients between 1320 and 1660K were obtained (table 107). They could be described by:
D(cm2/s) = 1.46 x 103exp[-5.02(eV)/kT]
The results supported the suggestion that self diffusion occurred via an extended interstitial mechanism.
H.J.Mayer, H.Mehrer, K.Maier: Institute of Physics Conference Series, 1976, 31, 186-93
Table 107
Self-Diffusion of Si
Temperature (C) | D (cm2/s) |
1047 | 1.13 x 10-16 |
1101 | 6.58 x 10-16 |
1146 | 1.71 x 10-15 |
1201 | 9.40 x 10-15 |
1247 | 2.81 x 10-14 |
1302 | 1.43 x 10-13 |
1337 | 2.62 x 10-13 |
1385 | 9.61 x 10-13 |