The addition of gold to palladium membranes produces many desirable effects for hydrogen purification, including improved tolerance of sulphur compounds, reduction in hydride phase formation, and, for certain compositions, improved hydrogen permeability. The focus of this work was to determine if sequential plating could be used to produce self-supported alloy membranes with equivalent properties to membranes produced by conventional metallurgical techniques such as cold-working. Sequential electroplating and electroless plating were used to produce freestanding planar Pd–Au membranes with Au contents ranging from 0 to 20 wt%, consisting of Au layers on both sides of a pure Pd core. Membranes were characterized by single-gas permeation measurements, scanning electron microscopy with energy dispersive X-ray spectroscopy (SEM/EDS), and high temperature, controlled-atmosphere X-ray diffraction. Sequentially plated foils tested without any prior annealing had significantly lower H2 permeabilities than either measured or literature values for homogeneous foils of equivalent composition. This effect appears to be due to the formation of stable gold-enriched surface layers. Pre-treatment of membranes to 1023K created membranes with hydrogen permeabilities equivalent to literature values, despite the fact that trace amounts of surface gold remained detectable with X-ray diffraction.

The Effects of Fabrication and Annealing on the Structure and Hydrogen Permeation of Pd–Au Binary Alloy Membranes. S.K.Gade, E.A.Payzant, H.J.Park, P.M.Thoen, J.D.Way: Journal of Membrane Science, 2009, 340[1-2], 227-33