Samples were implanted with 120keV S+ ions to doses of between 3 x 1013 and 1015/cm2 (table 21). They were capped with an 80nm-thick film of amorphous hydrogenated Si, into which As was doped to a concentration of 2 x 1020/cm3. The samples were then annealed in Ar gas (850 to 1000C, 0.25h) giving:
1 x 1015/cm2: D(cm2/s) = 2.0 x 10-9 exp[-0.80(eV)/kT]
5 x 1014/cm2: D(cm2/s) = 9.0 x 10-9 exp[-1.00(eV)/kT]
1 x 1014/cm2: D(cm2/s) = 4.2 x 10-7 exp[-1.50(eV)/kT]
5 x 1013/cm2: D(cm2/s) = 5.5 x 10-7 exp[-1.60(eV)/kT]
It was found that the diffusivity of S (table 22) could be described by the expression:
D = Dm[KQ2/(1 + KQ2)]
where K was a constant, Q was the implantation dose, and Dm was the diffusivity of a mobile complex.
M.Sakaguchi, K.Yokota, A.Shiomi, K.Hirai, H.Takano, M.Kumagai: Japanese Journal of Applied Physics, 1996, 35[1-8], 4203-8
Table 21
Diffusivity of Implanted S in GaAs
120keV S+ (/cm2) | Temperature (C) | D (cm2/s) |
1 x 1015 | 1000 | 1.4 x 10-12 |
1 x 1015 | 950 | 9.6 x 10-13 |
1 x 1015 | 900 | 7.1 x 10-13 |
1 x 1015 | 850 | 5.4 x 10-13 |
5 x 1014 | 1000 | 9.9 x 10-13 |
5 x 1014 | 950 | 7.9 x 10-13 |
5 x 1014 | 900 | 4.9 x 10-13 |
5 x 1014 | 850 | 3.0 x 10-13 |
1 x 1014 | 1000 | 5.0 x 10-13 |
1 x 1014 | 950 | 3.4 x 10-13 |
1 x 1014 | 900 | 1.3 x 10-13 |
5 x 1013 | 1000 | 2.6 x 10-13 |
5 x 1013 | 950 | 1.4 x 10-13 |