Serial sectioning was used to study the diffusion of 123Sn in monocrystalline material with a carrier concentration of about 1018/cm3. It was found that the concentration profiles were consistent with the existence of 2 diffusion coefficients (table 39): one which applied near to the surface,
200-300C: D (cm2/s) = 1.73 x 10-6 exp[-0.66(eV)/kT]
while the other applied deep within the specimen,
200-300C: D (cm2/s) = 1.8 x 10-3 exp[-0.80(eV)/kT]
Electromigration (180C, 0.14V/cm) was also studied, and the charge number of the diffusing 123Sn ion was found to be 1.02.
Diffusion of Sn in HgTe. F.A.Zaitov: Fizika Tverdogo Tela, 1971, 13[1], 278-9
Table 39
Diffusion of 123Sn in HgTe
Temperature (C) | Location | D (cm2/s) |
200 | near-surface | 1.0 x 10-13 |
250 | near-surface | 5.2 x 10-13 |
275 | near-surface | 9.1 x 10-13 |
300 | near-surface | 1.48 x 10-12 |
200 | interior | 1.3 x 10-12 |
250 | interior | 1.96 x 10-12 |
275 | interior | 4.2 x 10-12 |
300 | interior | 6.2 x 10-12 |