The effect of nitrogen incorporation into HfSiO on the electronic structure and band alignment of HfSiO films was investigated. N depth profile data obtained by medium-energy ion scattering showed that the concentration of N or the bonding or electronic state of N in the film was stable when the film was annealed at 950C, while the oxygen in HfSiON films was present in dissociated form, as evidenced by the unoccupied electronic state of O. The valence band offsets of the HfSiO films were strongly affected by N incorporation due to the presence of N in a 2p state. Moreover, a reduction in the conduction band offset of a HfSiO film was confirmed after the film was annealed in an atmosphere of N2. The unoccupied state of the O vacancy was responsible for the change in the conduction band offset. The results of ab-initio calculations for the density of states of HfSiO and HfSiON supercells were in agreement with the experimental results. The incorporation on N into HfSiO prevents the formation of a gap-state inside the band gap despite the fact that an O vacancy was generated in the film.

Effect of Nitrogen Incorporation and Oxygen Vacancy on Electronic Structure and the Absence of a Gap State in HfSiO Films. M.H.Jang, K.S.Jeong, K.B.Chung, J.W.Lee, M.H.Lee, M.H.Cho: Surface Science, 2012, 606[15–16], L64–8