An investigation was made of  electrical properties of anhydrous and hydrous forsterite crystal with 3.2wt% water by using first-principles calculations. The calculation results indicate that the pressure weakly affects the electrical properties of anhydrous forsterite. Two types of defect configuration involving the two hydrogen atoms in different positions were considered. Type 1 involved the entrapment of two hydrogen atoms in a Mg vacancy, which demonstrates little effect on the electronic density of states of the forsterite crystal. Type 2 corresponds to the replacement of one hydrogen atom into the Mg vacancy with the other one located in different orientations (free proton model). It was this configuration that can significantly change the density of states of the forsterite crystal. The gap energy of the free proton model derived at different orientations was in the range of 0.693 to 1.007eV.Electrical Properties of Hydrous Forsterite Derived from First-Principles Calculations. D.J.Wang, Z.Y.Liu, L.Yi, B.P.Shi: Chinese Physics Letters, 2011, 28[5], 059101