The transport properties of hydrogen were crucial to the kinetics of hydrogen storage in MgH2. First-principle calculations were used to identify the hydrogen diffusion paths and barriers and diffusion rates in three different MgH2 structures: equilibrium rutile, rutile with ball-milling-induced deformation twins and fluorite polymorph. Hydrogen vacancy mediated mechanism was applied when hydrogen diffusion was studied. It was observed that both hydrogen diffusion barriers in deformation twins and fluorite structure were lower compared to that in the equilibrium rutile. This was because the hydrogen diffusion was facilitated by new interstitial sites in the Mg lattice: a new hexahedral site formed by the reconstruction of Mg lattice at the twinning interface in the deformation twins and the octahedral sites in the fluorite structure. Furthermore, the hydrogen vacancy density effect on the diffusion barrier was estimated. The general trend was the higher the density of hydrogen vacancies, the lower the hydrogen diffusion barrier, the higher the diffusion rate. The results demonstrated how the hydrogen kinetics was altered by controlling the structure of the hydrides.

First Principle Study of Hydrogen Diffusion in Equilibrium Rutile, Rutile with Deformation Twins and Fluorite Polymorph of Mg Hydride. Tao, S.X., Kalisvaart, W.P., Danaie, M., Mitlin, D., Notten, P.H.L., Van Santen, R.A., Jansen, A.P.J.: International Journal of Hydrogen Energy, 2011, 36[18], 11802-9