The non-thermal effects of illumination upon surface diffusion at high temperatures were measured. It was found that the activation energies and pre-exponential factors for the diffusion of In changed upon illumination with photons having energies that were greater than the substrate band-gap:
n-type substrate, non-illuminated: D (cm2/s) = 1.0 x 103 exp[-1.78(eV)/kT]
n-type substrate, illuminated: D (cm2/s) = 4.0 x 101 exp[-1.48(eV)/kT]
p-type substrate, non-illuminated: D (cm2/s) = 1.0 x 103 exp[-1.78(eV)/kT]
p-type substrate, illuminated: D (cm2/s) = 4.0 x 104 exp[-2.10(eV)/kT]
These parameters decreased for n-type material, and increased for p-type material.
R.Ditchfield, D.Llera-RodrÃguez, E.G.Seebauer: Physical Review B, 2000, 62[20], 13710-20