The diffusion of 63Ni in single crystals was studied by using the radioactive surface decrease method at 450 to 800C. The results could be described by:
D (cm2/s) = 1.0 x 103 exp[-4.24(eV)/kT]
The data supported a dissociative diffusion mechanism for Ni diffusion. Rapid interstitial diffusion of Ni was followed by complex reactions of interstitials, with vacancies, which resulted in the particular concentration profiles of substitutional Ni. It was estimated that the activation energy for the diffusion of vacancies was equal to 1.91eV.
H.P.Bonzel: Physica Status Solidi, 1967, 20[2], 493-504
The best linear fits to the solute diffusion data ([124] to [129], [133] to [144], [146] to [176], [188] to [192], [196] to [211], [215] to [223], [234] to [242], [252] to [283], [292] to [298], [306] to [314]) yield:
Al: Ln[Do] = 0.45E – 32.8 (R2 = 0.81); As: Ln[Do] = 0.29E – 23.2 (R2 = 0.87);
Au: Ln[Do] = 0.16E – 12.4 (R2 = 0.16); B: Ln[Do] = 0.29E – 22.6 (R2 = 0.79);
Cu: Ln[Do] = 0.22E (R2 = 0.86); Fe: Ln[Do] = 0.62E – 15.8 (R2 = 0.53);
Ga: Ln[Do] = 0.20E - 16.9 (R2 = 0.78); Ge: Ln[Do] = 0.29E – 23.2.8 (R2 = 0.98);
H: Ln[Do] = 0.17E - 9.9 (R2 = 0.07); Li: Ln[Do] = 0.25E – 9.6 (R2 = 0.48);
Ni: Ln[Do] = 0.29E - 19.4 (R2 = 0.66); O: Ln[Do] = 0.34E – 21.6 (R2 = 0.95);
P: Ln[Do] = 0.35E - 27 (R2 = 0.94); Sb: Ln[Do] = 0.35E – 29.3 (R2 = 0.96);
Si: Ln[Do] = 0.33E - 29 (R2 = 0.86)