Secondary ion mass spectroscopy was used to measure the diffusion of deuterium in hydrogenated amorphous silicon. For a film deposited in a dc glow discharge in SiH4 at a substrate temperature of 315C, the diffusion data obeyed:
D(cm2/s) = 1.17 x 10-2exp[-1.53(eV)/kT]
This result implied that degradation of these films due to hydrogen out-diffusion at 100C would not be significant until after more than 104 years