The tracer diffusivities of 18O, on the ab-plane and in the c-direction, of monocrystalline samples were measured by using secondary ion mass spectrometry, at temperatures of between 250 and 350C and between 450 and 700C, respectively, under an O partial pressure of 1atm. It was found that the data (table 48) could be described by the expressions,

Dab (cm2/s) = 8 x 10-5 exp[-1.01(eV)/kT]

Dc (cm2/s) = 6 x 10-2 exp[-2.11(eV)/kT]

Diffusion of 18O in Bi2Sr2CuOx Single Crystals.

 M.Runde, J.L.Routbort, J.N.Mundy, S.J.Rothman, C.L.Wiley, X.Xu: Physical Review B, 1992, 46[5], 3142-4

 

 

Table 47

The c-Axis Diffusion of 18O in Monocrystalline Bi2Cu2Sr2CaOx

Temperature (C)

D (cm2/s)

400

2.96 x 10-17

500

2.42 x 10-15

600

1.13 x 10-13

700

2.47 x 10-12