Diffusion experiments were performed on B-implanted 6H-SiC between 1700 and 2100C. After diffusion, the B concentration profiles were measured by means of secondary ion mass spectrometry. Accurate modeling of B diffusion was achieved on the basis of a kick-out diffusion mechanism which involved only point defects on the Si sub-lattice. The fitting of experimental profiles yielded data, on the B interstitial-controlled B diffusion coefficient, which were in good agreement with published data. The analysis of B diffusion also provided data on the Si interstitial-controlled B diffusion coefficient which was related to the Si self-interstitial contribution to Si diffusion in SiC. This contribution was found to be 2 orders of magnitude lower than an extrapolation of published Si diffusion data.
Diffusion of Boron in Silicon Carbide. K.Rüschenschmidt, H.Bracht, M.Laube, N.A.Stolwijk, G.Pensl: Physica B, 2001, 308-310, 734-7
Table 70
Effective Diffusivities of B in SiC
Sample | Temperature (C) | D (cm2/s) |
implanted | 1600 | 6.7 x 10-12 |
implanted | 1700 | 1.3 x 10-11 |
implanted | 2050 | 2.5 x 10-11 |
buried layer | 1700 | 2.0 x 10-13 |