The serial sectioning technique was used to study the diffusion of 137Cs+ in single crystals. The data, for 450 to 750C, could be described by:
D (cm2/s) = 1.62 x 102 exp[-2.00(eV)/kT]
in the intrinsic range, and by:
D (cm2/s) = 2.97 x 10-3 exp[-1.20(eV)/kT]
in the extrinsic range.
F.Bénière, M.Bénière, M.Chemla: Journal de Chimie Physique et de Physicochimie Biologique, 1969, 66[5], 898-902
The best linear fits to the solute diffusion data ([382] to [383], [391] to [397], [403] to [405]) yield:
Cs: Ln[Do] = 0.29E – 9.9 (R2 = 0.73); Na: Ln[Do] = 0.57E – 22.4 (R2 = 0.99);
Sr: Ln[Do] = 0.55E – 20.5 (R2 = 0.51)