Diffusion in films which were as thin as 3.5nm was studied by using doped poly-Si/SiO2/Si samples. The data for B diffusion were described by:

D (cm2/s) = 3.1 x 10-1 exp[-4.2(eV)/kT]

It was found that a 2-boundary model could be used to characterize low-concentration B diffusion. At high B concentrations, an anomalous diffusion enhancement was detected with increasing annealing time and decreasing film thickness. The enhancement was attributed to the formation of a high-diffusivity layer.

T.Matsuura, J.Murota, N.Mikoshiba, I.Kawashima, T.Sawai: Journal of the Electrochemical Society, 1991, 138[11], 3474-80

The best linear fit to the solute diffusion data ([444] to [446]) yields:

B: Ln[Do] = 0.11E – 21.2 (R2 = 0.73)