Proton relaxation times were used to estimate H diffusivities in β-phase Ni5-yAlyLaHx, for y-values of between 0 and 1.2 (table 109). It was found that the substitution of Al significantly increased the observed activation energy, with a corresponding 2-fold increase in the diffusion coefficient at 300K (table 110).
NMR Studies of Hydrogen Diffusion in β-LaNi5−yAly Hydrides. R.C.Bowman: Solid State Communications, 1979, 32[7], 501-6
Table 111
Diffusivity of H in H-Storage Alloys
Alloy | D (cm2/s) |
Ni5La | 4.3 x 10-8 |
Ni4.5Al0.5La | 5.2 x 10-9 |
Ni4.0Cr0.4Mn0.3Al0.3La | 6.2 x 10-9 |
Ni1.4Zr | 3.4 x 10-9 |
Ni1.2Mn0.6V0.2Co0.1Zr | 2.7 x 10-9 |
Ni1.2Mn0.4Cr0.4Zr | 1.1 x 10-9 |