The room-temperature diffusivity and solubility of H were measured in Pd alloys, which contained up to 5at%Y, by using an electrolytic method. It was shown that the addition of Y increased both magnitudes. The behavior of H (table 156) was analyzed by using H potential models. It was suggested that Y atoms did not act as trapping centers for H atoms at room temperature. It was concluded that the addition of Y decreased the H site energy in Pd, and also lowered the activation energy for H diffusion. The decrease was attributed to a lattice expansion which was caused by the Y additions.

Hydrogen Diffusivity and Solubility in Pd-Y Alloys. O.Yoshinari, H.Matsuda, K.Fukuhara, K.Tanaka: Materials Transactions, 1997, 38[6], 508-13

 

Figure 35

Diffusivity of H in Pd-Y

(a: 0%Y, b: 2.6%Y, c: 4.98%Y, d: 8.1%Y, e: 10.1%Y)