The diffusion coefficient, heat of transport and solubility limit were determined by means of resistance measurements. The experiments were performed below room temperature, using H concentrations of up to 1.29at%. A very low activation energy (0.040eV) was found for diffusion. The heat of transport was 0.01eV. The solubility limit, as measured between 120 and 270K, was associated with a precipitation enthalpy of 0.13eV.
Diffusion Coefficient, Heat of Transport, and Solubility Limit of H In V. R.Heller, H.Wipf: Physica Status Solidi A, 1976, 33[2], 525-30
Table 183
Electromigration of H in V Alloys
Solute | Temperature (K) | Z*(e) |
- | 273 | 1.87 |
- | 299 | 1.75 |
- | 320 | 1.67 |
- | 327 | 1.69 |
- | 355 | 1.48 |
- | 397 | 1.43 |
- | 441 | 1.44 |
4%Cr | 273 | 1.66 |
4%Fe | 273 | 1.87 |
4%Mo | 273 | 1.90 |
4%Ti | 273 | 1.35 |