A sectioning technique was used to study the diffusion of 22Na in a diffusion couple which consisted of NaCl and NaBr single crystals, with their (100) crystal planes in contact. The self-diffusivity increased from 8 x 1010cm2/s, to a maximum of about 9 x 1010cm2/s at about 25at%NaCl, and then fell to about 3.4 x 1010cm2/s for pure NaCl. Sodium-Ion Movement in the Diffusional Zone of the NaCl-NaBr System. Y.E.Geguzin, V.I.Solunski, A.G.Shakhova: Fizika Tverdogo Tela, 1967, 9[4], 1254-5

 

Table 22

Self-Diffusion of 110Ag in NaBr-AgBr

Solid Solutions at 400C

 

AgBr

CdBr2

D (cm2/s)

0

0.0020

7.68 x 10-9

0.040

0.0030

1.49 x 10-8

0.070

0.0030

1.93 x 10-8

0.100

0.0050

3.62 x 10-8

0.150

0.020

2.15 x 10-7

0.174

0.030

3.16 x 10-7

0.20

0.040

5.16 x 10-7

0.216

0.040

6.23 x 10-7

0.269

0.040

6.55 x 10-7

0.288

0.040

7.20 x 10-7

0.320

0.040

8.66 x 10-7

1.0

0

5.16 x 10-6

1.0

0.090

6.28 x 10-6