Impedance measurements and chronopotentiometry methods were used to investigate the diffusion of Cd2+ in the melt. The impedance technique yielded a diffusivity of 1.40 x 10-5cm2/s at 450C and an activation energy of 6.6kcal/mol. The chronopotentiometric technique yielded corresponding figures of 1.35 x 10-5cm2/s and 6.3kcal/mol.

Diffusion Kinetics of the Electrolytic Extraction of Pb, Bi, Zn and Cd from Fused Chlorides. R.Y.Bek, A.S.Lifshits: Izv. Sib. Otd. Akad. Nauk SSSR - Khim. Nauk, 1970, 3, 58-63

 

Table 76

Diffusion of Cl in Molten KCl-LiCl Eutectic

 

Temperature (C)

D (cm2/s)

400

6.0 x 10-5

450

1.6 x 10-4

500

1.7 x 10-4

550

1.5 x 10-4