Oscillopolarographic methods were used to study the diffusion of Tl+ in the molten eutectic. The diffusivity, at temperatures ranging from 651 to 813K, could be described by:
log [D (cm2/s)] = 2.512 – 1420/T(K)
and the activation energy was equal to 26.55kJ/mol.
Oscillopolarographic Study of the Temperature Dependences of Diffusion Coefficients for a Series of Chlorides in LiCl-KCl. I.I.Naryshkin, V.P.Yurkinskii: Elektrokhimiya, 1969, 5[6], 871-2
Table 109
Diffusion of U in LiCl-KCl Melts at 728K
Material | Method | D(cm2/s) |
LiCl-KCl-UCl3 | cyclic voltammetry | 8.1 x 10-5 |
LiCl-KCl-UCl3 | chronopotentiometry | 3.47 x 10-4 |
LiCl-KCl-UCl3-UCl4 | cyclic voltammetry | 1.5 x 10-6 |
LiCl-KCl-UCl3-UCl4 | chronopotentiometry | 3.17 x 10-5 |