Chronopotentiometric methods were used to investigate the interdiffusion of Ag+ ions in melts. The diffusivity at 710C was equal to 6.95 x 10-5cm2/s. The data for temperatures ranging from 710 to 880C could be described by:
D (cm2/s) = 1.91 exp[-6.411(kcal/mol)/RT]
Interdiffusion Coefficient of the Ag Ion in Molten Alkali Chlorides by the Chronopotentiometric Method. S.Sternberg, C.Herdlicka: Revue Roumaine de Chimie, 1972, 17[1-2], 343-52
Table 141
Diffusion Parameters for Hf2+ in
Equimolecular NaCl-KCl Melts at 700 to 900C
HfCl2 (%) | Do (cm2/s) | Q (kcal/mol) |
0.1247 | 2.95 | 8.000 |
0.2913 | 2.61 | 7.900 |
0.6350 | 2.72 | 7.950 |
1.1247 | 2.73 | 7.950 |