The diffusion of Li+ was investigated by performing isotopic exchange between crystals, and solutions of C4H9Li in octane and cyclohexane. The exchange took place in 2 stages; exchange reaction in the surface layer, and subsequent diffusion in the interior of the solid phase. The diffusivity of Li at 18C was deduced to be equal to 4 x 10-18cm2/s.
G.Y.Ryskin, E.K.Shalkova: Zhurnal Fizicheskoi Khimii, 1977, 51[1], 43-6
Table 168
Isotope Effect for 6Li and 7Li Self-Diffusion
in LiF Single Crystals
Temperature (C) | Isotope Effect |
600 | 0.407 |
650 | 0.400 |
700 | 0.445 |
750 | 0.450 |