Measurements were made of the electrical conductivity of pure and Sr-doped (0.005 to 1.5mol%) single crystals. At temperatures below 400K, the Arrhenius plot exhibited 2 regions in the case of pure material. The lower-temperature region was attributed to the presence of so-called frozen defects. In the case of Sr-doped crystals, an additional straight-line section appeared in the Arrhenius plot; with a slope that indicated an activation energy of 0.61eV for the migration of cation vacancies.
Ionic Conductivity of KI Crystals. K.S.Cholokov, V.A.Grishukov: Izvestiya Vysshikh Uchebnykh Zavedenii Fizika, 1970, 13[8], 158-60
Table 203
Activation Energy for KI-RbI
Interdiffusion at 545 to 615C
KI (mol%) | Q (kcal/mol) |
30 | 44.80 |
40 | 46.00 |
50 | 45.60 |
60 | 43.00 |
70 | 40.00 |
80 | 38.70 |