Measurements were made of the electrical conductivity of pure and Sr-doped (0.005 to 1.5mol%) single crystals. At temperatures below 400K, the Arrhenius plot exhibited 2 regions in the case of pure material. The lower-temperature region was attributed to the presence of so-called frozen defects. In the case of Sr-doped crystals, an additional straight-line section appeared in the Arrhenius plot; with a slope that indicated an activation energy of 0.61eV for the migration of cation vacancies.

Ionic Conductivity of KI Crystals. K.S.Cholokov, V.A.Grishukov: Izvestiya Vysshikh Uchebnykh Zavedenii Fizika, 1970, 13[8], 158-60

 

Table 203

Activation Energy for KI-RbI

Interdiffusion at 545 to 615C

 

KI (mol%)

Q (kcal/mol)

30

44.80

40

46.00

50

45.60

60

43.00

70

40.00

80

38.70