The tracer diffusivities of 18O, on the ab-plane and in the c-direction, of monocrystalline samples were measured by using secondary ion mass spectrometry, at temperatures of between 250 and 350C and between 450 and 700C, respectively, under an O partial pressure of 1atm. It was found that the data (table 24) could be described by the expressions,
Dab (cm2/s) = 8 x 10-5 exp[-1.01(eV)/kT]
Dc (cm2/s) 6 x 10-2 exp[-2.11(eV)/kT]
M.Runde, J.L.Routbort, J.N.Mundy, S.J.Rothman, C.L.Wiley, X.Xu: Physical Review B, 1992, 46[5], 3142-4
Table 24
Diffusion of 18O in Bi2Sr2CuOx
Temperature (C) | Direction | D (cm2/s) |
250 | ab | 1.48 x 10-14 |
350 | ab | 5.29 x 10-13 |
450 | c | 1.44 x 10-16 |
550 | c | 6.04 x 10-15 |
650 | c | 2.36 x 10-13 |
700 | c | 8.16 x 10-13 |