An investigation was made of the electronic and ionic conductivities of La0.70Ca0.30Mn0.95Co0.05O3 perovskite. The ionic conductivities (table 79) were determined by using encapsulated zirconia micro-electrodes, and a Hebb-Wagner analysis of the current versus voltage curves.

P.Shuk, K.Künstler, W.Richter, U.Guth, L.Tichonova: Solid State Phenomena, 1994, 39-40, 103-6

 

 

 

 

Table 79

Oxide Ion Conductivities of La0.70Ca0.30Mn0.95Co0.05O3 Perovskite

 

Temperature(K)

PO2 (bar)

 (S/cm)

973

0.2

3.95

973

10-5

3.80

973

10-6

3.52

973

10-7

3.23

973

10-9

3.16

973

10-11

3.04

923

0.2

4.25

923

10-5

4.20

923

10-6

3.85

923

10-7

3.70

923

10-9

3.65

973

10-11

3.54

873

0.2

4.70

873

10-5

4.70

873

10-6

3.95

873

10-7

3.85

873

10-9

3.80

873

10-11

3.70