Nasicon-type compounds and solid solutions, where M was Li or Na, were investigated by using X-ray powder diffraction and ionic conductivity methods. The variation in ionic conductivity as a function of x was regular (table 165).

J.M.Winand, A.Rulmont, P.Tarte: Journal of Solid State Chemistry, 1991, 93[2], 341-9

 

 

 

Table 165

Ionic Conductivity of Hf2M(PO4)3-Type Solid Solutions

 

Material

Temperature (K)

 (S/cm)

Hf2Na(PO4)3

600

4.9 x 10-5

Hf2Na(PO4)3

400

5.1 x 10-7

Hf2Li(PO4)3

600

3.9 x 10-4

Hf2Li(PO4)3

400

1.5 x 10-5